Selective film growth for bottom-up gap filling

ABSTRACT

A method includes etching a portion of a semiconductor material between isolation regions to form a trench, forming a semiconductor seed layer extending on a bottom surface and sidewalls of the trench, etching-back the first semiconductor seed layer until a top surface of the semiconductor seed layer is lower than top surfaces of the isolation regions, performing a selective epitaxy to grow a semiconductor region from the semiconductor seed layer, and forming an additional semiconductor region over the semiconductor region to fill the trench.

PRIORITY CLAIM AND CROSS-REFERENCE

This application claims the benefit of the following provisionally filedU.S. Patent Application Ser. No. 62/552,005, filed Aug. 30, 2017, andentitled “Selective Film Growth for Bottom-Up Gap Filling,” whichapplication is hereby incorporated herein by reference.

BACKGROUND

The formation of fin field-effect transistors involves the formation ofrecesses, and then filling the recesses with a semiconductor material inorder to form semiconductor fins. For example, recesses may be formedbetween shallow trench isolation regions, and silicon germanium is grownin the recesses. With the increasingly down-scaling of the integratedcircuits, the aspect ratio of the recesses becomes increasingly higher.This causes the difficulty in filling the recesses. As a result, voidsand seams may occur in the semiconductor material that is filled in therecesses.

BRIEF DESCRIPTION OF THE DRAWINGS

Aspects of the present disclosure are best understood from the followingdetailed description when read with the accompanying figures. It isnoted that, in accordance with the standard practice in the industry,various features are not drawn to scale. In fact, the dimensions of thevarious features may be arbitrarily increased or reduced for clarity ofdiscussion.

FIGS. 1 through 23A illustrate the cross-sectional views of intermediatestages in the formation of a semiconductor fin and a Fin Field-EffectTransistor (FinFET) in accordance with some embodiments of the presentdisclosure.

FIGS. 23B, 23C, 23D, 24A and 24B illustrate the cross-sectional views ofFinFETs in accordance with some embodiments.

FIG. 25 illustrates a process flow for gap-filling and the formation ofa FinFET in accordance with some embodiments.

DETAILED DESCRIPTION

The following disclosure provides many different embodiments, orexamples, for implementing different features of the invention. Specificexamples of components and arrangements are described below to simplifythe present disclosure. These are, of course, merely examples and arenot intended to be limiting. For example, the formation of a firstfeature over or on a second feature in the description that follows mayinclude embodiments in which the first and second features are formed indirect contact, and may also include embodiments in which additionalfeatures may be formed between the first and second features, such thatthe first and second features may not be in direct contact. In addition,the present disclosure may repeat reference numerals and/or letters inthe various examples. This repetition is for the purpose of simplicityand clarity and does not in itself dictate a relationship between thevarious embodiments and/or configurations discussed.

Further, spatially relative terms, such as “underlying,” “below,”“lower,” “overlying,” “upper” and the like, may be used herein for easeof description to describe one element or feature's relationship toanother element(s) or feature(s) as illustrated in the figures. Thespatially relative terms are intended to encompass differentorientations of the device in use or operation in addition to theorientation depicted in the figures. The apparatus may be otherwiseoriented (rotated 90 degrees or at other orientations) and the spatiallyrelative descriptors used herein may likewise be interpretedaccordingly.

A bottom-up gap-filling method and the Fin Field-Effect Transistors(FinFETs) formed based on the semiconductor material filling the gapsare provided in accordance with various exemplary embodiments. Theintermediate stages of the gap-filling and the formation of FinFETs areillustrated in accordance with some embodiments. Some variations of someembodiments are discussed. Throughout the various views and illustrativeembodiments, like reference numbers are used to designate like elements.It is appreciated that in the illustrative embodiments, germanium andsilicon are used as examples to discuss the concept of the presentdisclosure, while other semiconductor materials such as silicon carbon,III-V compound semiconductors, or the like may also be used.

FIGS. 1 through 23A illustrate the cross-sectional views of intermediatestages in the formation of a FinFET in accordance with some embodimentsof the present disclosure. The steps shown in FIGS. 1 through 23A arealso reflected schematically in the process flow shown in FIG. 24.

FIG. 1 illustrates a cross-sectional view of substrate 20, which is apart of a semiconductor wafer. Substrate 20 may be a semiconductorsubstrate such as a silicon substrate, a silicon carbon substrate, asilicon-on-insulator substrate, or a substrate formed of othersemiconductor materials. Substrate 20 may also include othersemiconductor materials such as silicon germanium, III-V compoundsemiconductor materials. Substrate 20 may be lightly doped with a p-typeor an n-type impurity.

FIG. 2 illustrates the formation of trenches 24. In accordance with someembodiments of the present disclosure, a pad oxide layer and a hard masklayer (not shown) are formed over substrate 20, and are then patterned.In accordance with some embodiments of the present disclosure, the padoxide is formed of silicon oxide, which may be formed by oxidizing a topsurface portion of semiconductor substrate 20. The hard mask may beformed of silicon nitride, silicon oxynitride, carbo-nitride, or thelike. The patterned hard mask and pad oxide layer are used as an etchingmask to etch substrate 20, so that trenches 24 are formed.

Trenches 24 extend into semiconductor substrate 20, and have lengthwisedirections parallel to each other. Although two trenches 24 areillustrated, there may be a plurality of trenches, such as 5, 10, ormore trenches formed, which are parallel to each other. Trenches 24 mayhave equal length and equal pitch. Semiconductor substrate 20 hasremaining portions between neighboring trenches 24, and the remainingportions are referred to substrate portions 20′ hereinafter. Althoughone substrate portion 20′ is illustrated for simplicity, there may be aplurality of substrate portions 20′, which may have a uniform pitch anda uniform width. In accordance with some embodiments of the presentdisclosure, height H1 of substrate portion 20′ is in the range betweenabout 30 nm and about 120 nm. Width W1 of substrate portion 20′ may bein the range between about 5 nm and about 20 nm. It is appreciated thatthe values recited throughout the description are examples, anddifferent values may also be adopted without changing the principle ofthe present disclosure.

Next, as shown in FIG. 3, isolation regions 26, which are alternativelyreferred to as Shallow Trench Isolation (STI) regions 26, are formed intrenches 24 (FIG. 2). The respective process step is illustrated as step202 in the process flow 200 as shown in FIG. 24. The formation of STIregions 26 may include forming a dielectric liner (not shown separately)in trenches 24, with the dielectric liner being formed on the exposedsurfaces of semiconductor substrate 20, and filling remaining trenches24 with a dielectric material(s). The dielectric liner may be a siliconoxide layer formed through thermal oxidation, so that a surface layer ofthe semiconductor substrate 20 is oxidized to form a silicon oxide. Theremaining trenches 24 may be filled using Flowable Chemical VaporDeposition (FCVD), spin-on coating, or the like. A planarization stepsuch as Chemical-Mechanical Polish (CMP) or mechanical grinding is thenperformed to level the top surface of the filled dielectric materialwith the top surface of the hard mask (not shown). After the CMP, thehard mask is removed. Alternatively, the polish stops on the topsurfaces of STI regions 26. In a top view of the structure shown in FIG.3, each substrate portion 20′ may be an elongated strip (which has auniform width) encircled by the respective STI regions 26, or may be astrip with the opposite ends connected to bulk portions of semiconductorsubstrate 20.

An anneal process may be performed. In accordance with some exemplaryembodiments of the present disclosure, the anneal is performed in anoxygen-containing environment. The annealing temperature may be higherthan about 200° C., for example, in a temperature range between about200° C. and about 700° C. During the anneal, an oxygen-containingprocess gas is conducted into the process chamber in which the wafer isplaced. The oxygen-containing process gas may include oxygen (O₂), ozone(O₃), or combinations thereof. Steam (H₂O) may also be used. The steammay be used without oxygen (O₂) or ozone, or may be used in combinationwith oxygen (O₂) and/or ozone.

Referring to FIG. 4, substrate portion 20′ is recessed, forming trench28 between neighboring STI regions 26. The respective process step isillustrated as step 204 in the process flow 200 as shown in FIG. 24. Inaccordance with some embodiments of the present disclosure, the etchingis performed through dry etching. The etching gas may include a mixtureof HBr, Cl₂, and O₂, or a fluorine-containing gas such as CF₂, C₂F₆,CF₄, NF₃, SF₆ or the like. The etching may also be performing using wetetch, and the etchant may include KOH, tetramethylammonium hydroxide(TMAH), HF/HNO₃/H₂O (a mixture), CH₃COOH, NH₄OH, H₂O₂, or Isopropanol(IPA). In accordance with some embodiments of the present disclosure,the bottom of trench 28 is higher than the bottom surfaces of STIregions 26. In accordance with alternative embodiments of the presentdisclosure, the bottom of trench 28 is substantially level with thebottom surfaces of STI regions 22. Height H2 of trench 28 may be in therange between about 20 nm and about 100 nm. Width W2 of trench 28 may bein the range between about 5 nm and about 20 nm. The aspect ratio oftrench 28 is greater than about 4, and may be in the range between about4 and about 20.

A well implantation may be performed to implant an n-type impurity or ap-type impurity into substrate 20 to form a well region, which extendsto a level lower than bottom surfaces of STI regions 26. Theconductivity type of the dopant introduced in the well implantation isopposite to the conductivity type of the subsequently formed FinFET. Forexample, when a p-type FinFET (with p-type source/drain regions) is tobe formed, the well implantation includes implanting an n-type impuritysuch as phosphorus or arsenic. When an n-type FinFET (with n-typesource/drain regions) is to be formed, the well implantation includesimplanting a p-type impurity such as boron or indium. A further annealmay be performed after the well implantation.

Referring to FIG. 5, semiconductor seed layer 30 is deposited throughepitaxy. The respective process step is illustrated as step 206 in theprocess flow 200 as shown in FIG. 24. The temperature for the depositionis selected, so that at least the portion of seed layer directlydeposited on the exposed surface of substrate portion 20′ is grownthrough epitaxy. In accordance with some embodiments of the presentdisclosure, the temperature of the deposition is in the range betweenabout 350° C. and about 700°.

The deposition of semiconductor seed layer 30 is nonselective, and hencesemiconductor seed layer 30 is formed on both the exposed top surface ofthe remaining substrate portion 20′ and the sidewalls and the topsurfaces of STI regions 26. Semiconductor seed layer 30 is formed as aconformal layer, and is formed using a conformal deposition method suchas Atomic Layer Deposition (ALD) or Chemical Vapor Deposition (CVD). Forexample, the thickness T1 of the horizontal portions and thickness T2 ofthe vertical portions of semiconductor seed layer 30 may have adifference smaller than about 20 percent or smaller than about 10percent of either one of thicknesses T1 and T2.

The precursor for forming semiconductor seed layer 30 may include asilicon-containing precursor such as SiH₄, Si₂H₆, Si₂Cl₆, Si₂H₄Cl₂, themixture thereof, or the like if seed layer 30 includes silicon. Theprecursor may include a germanium-containing precursor such as GeH₄,Ge₂H₆, the mixture thereof, or the like if seed layer 30 includesgermanium. When seed layer 30 includes SiGe, the precursor may includeboth a silicon-containing precursor (as discussed above) and agermanium-containing precursor (as discussed above). The pressure of theprocess gas for the deposition may be in the range between about 0.15Torr and about 30 Torr. In accordance with some embodiments of thepresent disclosure, semiconductor seed layer 30 is a silicon layer freefrom germanium. In accordance with alternative embodiments of thepresent disclosure, semiconductor seed layer 30 is a silicon germaniumlayer. In accordance with yet alternative embodiments of the presentdisclosure, semiconductor seed layer 30 is a germanium layer free fromsilicon. The material of semiconductor seed layer 30 is affected by thedesirable material of semiconductor fin 60 as shown in FIG. 23A. Thegermanium percentage in seed layer 30 may be equal to or lower than thegermanium percentage in semiconductor fin 60, and may be equal to orhigher than the germanium percentage in substrate 20. Semiconductor seedlayer 30 may have a thickness in the range between about 1 nm and about5 nm. In accordance with alternative embodiments, seed layer 30 isformed of another semiconductor material such as silicon carbon, a III-Vcompound semiconductor material, or the like.

After the deposition of semiconductor seed layer 30, protection layer 32(FIG. 6) is formed to fill the remaining portion of trench 28. Therespective process step is illustrated as step 208 in the process flow200 as shown in FIG. 24. The resulting structure is shown in FIG. 6. Inaccordance with some embodiments of the present disclosure, protectionlayer 32 is formed of a photo resist. In accordance with alternativeembodiments, protection layer 32 is formed of another material that isdifferent from the material of STI regions 26. For example, protectionlayer 32 may be formed of an inorganic material such as a spin-on glass,silicon nitride, silicon carbide, or an organic material (which may be apolymer) such as polyimide or polybenzoxazole (PBO). The property ofprotection layer 32 is different from that of STI regions 26, so that inthe subsequent etching of semiconductor seed layer 30, STI regions 26are not damaged. Protection layer 32 may have a substantially planar topsurface, which may be caused by spin-on coating when protection layer 32is formed of a photo resist, a polymer, or a spin-on dielectricmaterial. In accordance with some embodiments, when the top surface ofprotection layer 32 is not planar as-formed, a planarization step suchas CMP or mechanical grinding is performed. The planarization may bestopped at any time before semiconductor seed layer 30 is exposed. Theplanarization may also be stopped using semiconductor seed layer 30 orSTI regions 26 as a stop layer. The top surface of the resultingprotection layer 32 may thus be higher than, lower than, or level with,the top surface of STI regions 26, and may be higher than, lower than,or level with, the top surface of seed layer 30.

FIG. 7 illustrates the etch-back of protection layer 32. The etch-backis symbolized by arrows 34. The respective process step is illustratedas step 210 in the process flow 200 as shown in FIG. 24. The etch-backmay include a dry etch and/or a wet etch. Furthermore, the etch-back maybe isotropic or anisotropic. In accordance with some embodiments of thepresent disclosure, the etch-back is performed using an etchant thatattacks protection layer 32, but doesn't attack semiconductor seed layer30 and STI regions 26. As a result of the etch-back of protection layer32, the remaining protection layer 32 is recessed to occupy a bottomportion of trench 28. The top surface of the remaining protection layer32 may be substantially planar or slightly curved.

FIG. 8 illustrates the etching-back of semiconductor seed layer 30. Therespective process step is illustrated as step 212 in the process flow200 as shown in FIG. 24. In accordance with some embodiments of thepresent disclosure, the etch-back of semiconductor seed layer 30 isperformed through a wet etch using ammonia solution (HN₄OH) when seedlayer 30 includes silicon. In accordance with alternative embodiments ofthe present disclosure, the etch-back is performed through a dry etchusing a fluorine-containing gas such as CF₄, CHF₃, CH₂F₂, or the like.In the etching, due to the protection of protection layer 32, the bottomportions of semiconductor seed layer 30 between protection layer 32 andSTI regions 26 are not etched. The top portions of semiconductor seedlayer 30 are removed in the etching, and the resulting structure isshown in FIG. 8.

In accordance with alternative embodiments of the present disclosure,instead of etching protection layer 32 and semiconductor seed layer 30in separate steps, both protection layer 32 and semiconductor seed layer30 are etched in a common etching step using the same etchant. Sincesemiconductor seed layer 30 is thin, keeping the etching selectivitymoderate (not too high) is able to achieve the simultaneous etching ofprotection layer 32 and semiconductor seed layer 30. The etchingselectivity is the ratio of the etching rate of protection layer 32 tothe etching rate of semiconductor seed layer 30. For example, dependingon the materials of semiconductor seed layer 30 and protection layer 32,a mixture of two etching gases may be used, with one etching gas usedfor etching semiconductor seed layer 30, and the other etching gas usedfor etching protection layer 32. In accordance with other embodiments, asingle etching gas or etching solution that attacks both semiconductorseed layer 30 and protection layer 32 is used.

After the etching of the upper portions of semiconductor seed layer 30,protection layer 32 is removed, for example, in an isotropic etchingprocess (dry or wet), depending on the material of protection layer 32.The respective process step is illustrated as step 214 in the processflow 200 as shown in FIG. 24. The resulting structure is shown in FIG.9, in which the remaining seed layer 30 has a shape of a basin, whichincludes a bottom portion and sidewall portions. The remaining height H3may be thinner than (W2)/2 to prevent Ge-growth-induced sidewall mergein the subsequent bottom-up growth of semiconductor region 36 (as shownin FIG. 10). The remaining height H3 of semiconductor seed layer 30 maybe in the range between about 3 nm and about 10 nm. The recessing depth(H2−H3) of semiconductor seed layer 30 may be greater than about 10 nm,and may be in the range between about 10 nm and about 107 nm. The ratioof H3/H2 may be in the range between about 2 and about 33.

FIG. 10 illustrates the selective epitaxy of semiconductor region 36.The respective process step is illustrated as step 216 in the processflow 200 as shown in FIG. 24. Epitaxy region 36 may be a silicongermanium region in accordance with some embodiments of the presentdisclosure. For example, the germanium atomic percentage may be anyvalue in the range between (and including) 0 percent and 100 percent. Inaccordance with alternative embodiments of the present disclosure,epitaxy region 36 is a germanium region with no silicon therein. Epitaxyregion 36 may also be formed of other semiconductor material such assilicon carbon or a III-V compound semiconductor.

Depending on whether epitaxy region 36 is a silicon region, silicongermanium region, or germanium region, the respective process gas mayinclude silane (SiH₄), germane (GeH₄), or the mixture of silane andgermane. Also, an etching gas such as hydrogen chloride (HCl) may beadded into the process gas to achieve selective growth, so that epitaxyregion 36 is grown from semiconductor seed layer 30, and not from theexposed surfaces of STI regions 26. In accordance with some embodimentsof the present disclosure, an n-type impurity-containing process gas(such as a phosphorous-containing process gas) or a p-type impuritycontaining process gas (such as a boron-containing process gas) isincluded in the precursor, so that epitaxy region 36 is in-situ doped tothe same conductivity type as the well region. In accordance withalternative embodiments of the present disclosure, no n-type impuritycontaining process gas and p-type impurity containing process gas isincluded in the process gas for forming epitaxy region 36.

The top surface of epitaxy region 36 may have various shapes, and may bea rounded top surface, a faceted top surface, or have another shape. Thetop surface of epitaxy region 36 may have convex shape or a concaveshape (refer to FIGS. 23C and 23D). For example, FIG. 23C illustratesthat the top surface of epitaxy region 36 has a convex shape thatincludes facets. FIG. 23D illustrates that the top surface of epitaxyregion 36 has a concave shape, also including facets. The facets may bestraight, and includes horizontal facets and tilted facets. Thedifferent shapes of the top surfaces of epitaxy region 36 are theresults of different process conditions, different duration of theepitaxy, or the like.

Through the process steps shown in FIGS. 5 through 10, trench 28 ispartially filled in a bottom-up style. Comparing FIG. 4 and FIG. 10, itis noted that the trench 28 as shown in FIG. 10 has a reduced aspectratio than the trench 28 shown in FIG. 4. Reducing the aspect ratio ofrecess may reduce the likelihood of incurring void in the subsequentgap-filling of trench 28.

FIGS. 11 through 15 illustrate the further partial filling of trench 28in accordance with some embodiments of the present disclosure. Theprocess steps are represented by looping the process back to step 206 inthe process flow shown in FIG. 24. Steps 206, 208, 210, 212, 214, and216 as shown in FIG. 24 are repeated. Referring to FIG. 11,semiconductor seed layer 40 is deposited. The temperature for thedeposition is selected, so that the portion of seed layer 40 directlydeposited on the exposed surface of semiconductor region 36 isepitaxially grown. The material of semiconductor seed layer 40 may beselected from the same group of candidate materials for formingsemiconductor seed layer 30. Furthermore, the formation method ofsemiconductor seed layer 40 may be selected from the same group ofcandidate methods for forming semiconductor seed layer 30. In accordancewith some embodiments of the present disclosure, semiconductor seedlayer 40 and semiconductor seed layer 30 are formed of the same materialand have the same composition. In accordance with alternativeembodiments of the present disclosure, semiconductor seed layer 40 andsemiconductor seed layer 30 have different compositions. Throughout thedescription, when two layers are referred to as having the samecomposition, it means that the two layers have same types of elements,and the percentages of the elements in two layers are the same as eachother. Conversely, when two layers are referred to as having differentcompositions, it means that one of the two layers either has at leastone element not in the other layer, or the two layers have the sameelements, but the percentages of the elements in two layers aredifferent from each other. For example, semiconductor seed layer 30 maybe formed of silicon or silicon germanium, while semiconductor seedlayer 40 may be formed of silicon or silicon germanium, with thegermanium percentage in semiconductor seed layer 40 being equal to orhigher than the germanium percentage in semiconductor seed layer 30.

The deposition of semiconductor seed layer 40 is also nonselective, andhence semiconductor seed layer 40 is formed on both semiconductor region36 and STI regions 26. Semiconductor seed layer 40 is formed as aconformal layer, with a thickness in the range between about 1 nm andabout 5 nm, for example.

After the deposition of semiconductor seed layer 40, protection layer 42is formed to fill the remaining portion of trench 28 (FIG. 11). Theresulting structure is shown in FIG. 12. In accordance with someembodiments of the present disclosure, protection layer 42 is formed ofa material selected from the same candidate material for formingprotection layer 32, which may be a photo resist, an inorganic material,or an organic material. The property of protection layer 42 is differentfrom that of STI regions 26, so that in the subsequent etching ofsemiconductor seed layer 40, STI regions 26 are not damaged. The topsurface of protection layer 42 is made substantially planar, which maybe achieved by spin coating and/or planarization. The top surface of theresulting protection layer 42 may be higher than, lower than, or levelwith the top surface of STI regions 26, and may be higher than, lowerthan, or level with the top surface of seed layer 40.

FIG. 13 illustrates the etch-back of protection layer 42 andsemiconductor seed layer 40. The resulting process steps may includeetching protection layer 42 first, followed by the etching ofsemiconductor seed layer 40. Alternatively, protection layer 42 andsemiconductor seed layer 40 are etched simultaneously in a commonprocess. The etching process may be similar to what is used in theetching of protection layer 32 and semiconductor seed layer 30, asdiscussed referring to FIGS. 7 and 8.

After the removal of semiconductor seed layer 40, protection layer 42 isremoved, for example, in an isotropic etching process, depending on thematerial of protection layer 42. The removal of protection layer 52 maybe achieved through dry etch or wet etch. The resulting structure isshown in FIG. 14.

FIG. 15 illustrates the selective epitaxy of semiconductor region 46.Epitaxy region 46 may be a silicon germanium region. The germaniumatomic percentage may be any value in the range between (and including)0 percent and 100 percent in accordance with some embodiments. Inaccordance with alternative embodiments of the present disclosure,epitaxy region 46 is a germanium region with no silicon therein.

Depending on whether epitaxy region 46 is a silicon region, silicongermanium region, or germanium region, the process gas may includesilane, germane, or the mixture of silane and germane. The formationprocess may be similar to the formation of epitaxy region 36, and henceis not repeated herein. In accordance with some embodiments, epitaxyregion 46 has a same composition as epitaxy region 36. In accordancewith alternative embodiments, epitaxy region 46 has a compositiondifferent from that of epitaxy region 36. For example, both epitaxyregions 36 and 46 may be formed of silicon germanium, and epitaxy region46 may have a germanium percentage higher than the germanium percentageof epitaxy region 36.

Through the process steps shown in FIGS. 11 through 15, the aspect ratioof trench 28 is further reduced to be than that of the trench 28 asshown in FIG. 10. In accordance with some embodiments of the presentdisclosure, the process as shown in FIGS. 11 through 15 may be repeatedto form more seed layers and epitaxy regions over epitaxy region 46 tofurther fill trench 28 in a bottom-up style, and the aspect ratio oftrench 28 is further reduced. The corresponding process is achieved byrepeating steps 206, 208, 210, 212, 214, and 216 as shown in FIG. 24.For example, FIGS. 16, 17, 18, and 19 illustrate the process for formingsemiconductor seed layer 50 and epitaxy regions 56, in which protectionlayer 52 is used to define the height of seed layer 50. The processdetails are similar to what are discussed referring to FIGS. 11 through15, and the details are not repeated herein.

Semiconductor seed layer 50 may be formed of a same material as, or adifferent material than, that of semiconductor seed layers 30 and 40.For example, semiconductor seed layer 50 may be formed of silicon orsilicon germanium. When formed of silicon germanium, the germaniumpercentage of semiconductor seed layer 50 may be equal to or greaterthan the germanium percentages of semiconductor seed layers 40 and 30.Epitaxy region 56 also may be formed of a same material as, or adifferent material than, that of epitaxy regions 36 and 46. For example,epitaxy region 56 may be formed of silicon germanium or germaniumwithout silicon. When formed of silicon germanium, the germaniumpercentage of epitaxy region 56 may be equal to or greater than thegermanium percentages of epitaxy regions 36 and 46.

FIG. 20 schematically illustrates the deposition and the etch-back ofmore semiconductor seed layers and semiconductor regions. Thesemiconductor seed layers are shown as layers 57 (including layers 57Aand 57B, while more or fewer may be formed). The semiconductor regionsare shown as layers 58 (including layers 58A and 58B, while more orfewer may be formed). The details of the materials and the formationprocess may be found from the candidate materials and processes forforming the underlying semiconductor seed layers 30, 40, and 50 andsemiconductor regions 36, 46, and 56. In accordance with someembodiments of the present disclosure, the height of each of the seedlayers 57 (and also 30, 40, and 50) may also be smaller than a half ofwidth W2 of the respective trench to prevent the merge of the portionsof semiconductor regions grown from the opposite sidewall portions ofthe respective seed layers. It is appreciated that the total count ofall seed layers may be any number equal to or higher than two, althoughfive seed layers are illustrated as an example.

FIG. 21 illustrates the planarization (such as CMP or mechanicalgrinding) of semiconductor region 58B, so that the top surface of topsemiconductor region 58B is coplanar with the top surfaces of STIregions 26. Also, after the planarization, the top edge of the top seedlayer 57B may be level with (as illustrated) or lower than the topsurface of the respective semiconductor region 58B, and dashed line 59schematically illustrates the level of the top edges of seed layer 57Bin accordance with some embodiments.

In accordance with some embodiments of the present disclosure, epitaxyregions 58 are formed of silicon germanium, germanium, or otherapplicable semiconductor materials. Furthermore, when formed of silicongermanium, the germanium percentage of epitaxy regions 58A and 58B maybe equal to or higher than any one of the germanium percentage in seedlayers 30 and 40 and epitaxy regions 36, 46, and 56. For example, thegermanium percentage in epitaxy region 58A and 58B may be in the rangebetween, and including, about 30 percent and about 100 percent. Theformation of epitaxy region 58 may be in-situ with the formation ofepitaxy region 56, with no vacuum break there between.

It is appreciated that in the above-discussed embodiments, the epitaxyregions 36, 46, and 56, and seed layers 30, 40, and 50 are referred toas including silicon and/or germanium as an example, the epitaxy regionsmay also be formed of other applicable semiconductor materials such assilicon, silicon carbon, III-V compound semiconductor materials, or thelike.

Next, STI regions 26 as shown in FIG. 21 are recessed to formsemiconductor fin 60, as illustrated in FIG. 22. The respective processstep is illustrated as step 218 in the process flow 200 as shown in FIG.24. The recessing of STI regions 26 may be performed using a dry etchprocess or a wet etch process. In accordance with some embodiments ofthe present disclosure, the recessing of STI regions 26 is performedusing a dry etch method, in which the process gases include NH₃ and HF.In accordance with alternative embodiments of the present disclosure,the recessing of STI regions 26 is performed using a wet etch method, inwhich the etchant solution is a dilution HF solution, which may have anHF concentration lower than about 1 percent.

The protruding portion of epitaxy regions and the respective seedlayers, which protrudes higher than the top surfaces of the remainingSTI regions 26, is referred to as semiconductor fin 60 hereinafter. Theheight H5 of semiconductor fin 60 may be in the range between about 10percent and about 50 percent of height H1 (FIG. 2) of the originalsubstrate portion 20′.

After STI regions 26 are recessed to form semiconductor fin 60, aplurality of process steps is performed on semiconductor fin 60, whichprocess steps may include well implantations, gate stack formation, aplurality of cleaning steps, and the like. A FinFET is thus formed. Anexemplary FinFET 62 is illustrated in FIG. 23A, which also shows theformation of gate stack 68. Gate stack 68 includes gate dielectric 64 onthe top surfaces and sidewalls of fin 60, and gate electrode 66 overgate dielectric 64. The respective process step is illustrated as step220 in the process flow 200 as shown in FIG. 24. Gate dielectric 64 maybe formed through a thermal oxidation process, and hence may includethermal silicon oxide. The formation of gate dielectric 64 may alsoinclude a deposition step, and the resulting gate dielectric 64 mayinclude a high-k dielectric material or a non-high-k dielectricmaterial. Gate electrode 66 is then formed on gate dielectric 64. Gatedielectric 64 and gate electrode 66 may be formed using a gate-firstapproach or a gate-last approach.

FIG. 24A illustrates FinFET 62 In accordance with some embodiments ofthe present disclosure. In these embodiments, bottom seed layer 57Aextends slightly lower than the top surfaces of STI regions 26. Theportions of strip 20′ underlying bottom seed layer 57A is a part of theoriginal substrate 20. There may not be any seed layer that is entirelylower than the top surfaces of STI regions 26. Depth D1, which is thedepth of seed layer 57A extending below the top surfaces of STI regions26, may be greater than about 5 nm.

FIG. 23B illustrates a cross-sectional view of FinFET 62, wherein thecross-sectional view is obtained from the plane containing line 23B-23Bin FIG. 23A. As shown in FIG. 23B, a plurality of gate stacks 68 isformed on semiconductor fin 60, and source and drain regions 70 areformed between gate stacks 68. The respective process step isillustrated as step 222 in the process flow 200 as shown in FIG. 24.Source and drain regions 70 may be formed by etching the portions of thesemiconductor fin 60 between gate stacks 68, and epitaxially growinganother semiconductor material such as silicon phosphorus, siliconcarbon phosphorus, silicon germanium boron, germanium boron, III-Vcompound semiconductor, or other applicable materials. The remainingportions of semiconductor fin 60 are separated from each other by commonsource regions and common drain regions 70. The gate stacks 68 may beinterconnected, the source regions 70 may be interconnected, and thedrain regions 70 may be interconnected to form FinFET 62.

As also shown in FIG. 23B, semiconductor seed layers 30, 40, 50, 57A and57B and epitaxy regions 36, 46, 56, 58A, and 58B in combination maycontinuously extend below a plurality of gate stacks 68 and a pluralityof source and drain regions 70. The composite structure including thealternating seed layers and epitaxy semiconductor regions may bedistinguishable (for example, through Transmission Electron Microscopy(TEM), Scanning Electron Microscopy (SEM), Secondary Ion MassSpectrometry (SIMS) or the like) when there is enough difference in thecompositions of these layers and regions. Alternatively, the compositestructure including the alternating seed layers and epitaxysemiconductor regions may not be distinguishable if there is no enoughdifference in the compositions of these layers and regions, and/or thedifferences are reduced by the annealing process.

FIG. 24B illustrates a cross-sectional view of FinFET 62 in accordancewith some embodiments of the present disclosure. The cross-sectionalview is obtained from the plane containing 24B-24B in FIG. 24A. Seedlayer 57A is a bottom seed layer in accordance with some embodiments.

FIGS. 23A and 23B also illustrated some examples in which the uppersemiconductor seed layer may be, or may not be merged with the lowersemiconductor seed layer. For example, seed layer 40 is illustrated asbeing in contact with seed layer 30 as an example, and seed layer 50 isillustrated as being spaced apart from seed layer 40 by a portion ofepitaxy region 46 as another example. It is noted that these are merelyexamples, and whether a seed layer contacts the underlying seed layerdepends on the process such as how long the epitaxy regions 36 and 46are grown.

The embodiments of the present disclosure have some advantageousfeatures. By forming a semiconductor seed layer at the bottom of atrench and performing selective epitaxy, the trench is filled bottom-up.When the bottom portion of the trench is partially filled, the aspectratio of the trench is reduced, and the remaining trench can be filledwithout generating voids.

In accordance with some embodiments of the present disclosure, a methodincludes etching a portion of a semiconductor material between isolationregions to form a trench, forming a semiconductor seed layer extendingon a bottom surface and sidewalls of the trench, etching-back the firstsemiconductor seed layer until a top surface of the semiconductor seedlayer is lower than top surfaces of the isolation regions, performing aselective epitaxy to grow a semiconductor region from the semiconductorseed layer, and forming an additional semiconductor region over thesemiconductor region to fill the trench. In an embodiment, theetching-back the first semiconductor seed layer comprises: forming aprotection layer over the first semiconductor seed layer; etching-backthe protection layer, wherein the etching-back the first semiconductorseed layer is performed using the protection layer as an etching mask;and before the first semiconductor seed layer is grown, removing theprotection layer. In an embodiment, the forming the protection layercomprises dispensing a photo resist. In an embodiment, the firstsemiconductor seed layer comprises horizontal portions and verticalportions having thicknesses close to each other. In an embodiment, afterthe first semiconductor seed layer is etched back, the firstsemiconductor seed layer has a basin shape. In an embodiment, theforming the first semiconductor seed layer is nonselective, and thefirst semiconductor seed layer is grown from both surfaces of theisolation regions and a top surface of the semiconductor material. In anembodiment, the forming the first semiconductor seed layer comprisesgrowing a silicon layer, with the silicon layer free from germanium. Inan embodiment, the forming the first semiconductor seed layer comprisesgrowing a silicon germanium layer. In an embodiment, the method furtherincludes forming a second semiconductor seed layer over the firstsemiconductor region, wherein the second semiconductor seed layercomprises a first portion on top surfaces of the isolation regions, anda second portion extending into the trench; etching-back the secondsemiconductor seed layer; and performing a second selective epitaxy togrow a second semiconductor region from the second semiconductor seedlayer, wherein the additional semiconductor region is formed over thesecond semiconductor region.

In accordance with some embodiments of the present disclosure, a methodincludes forming isolation regions extending into a semiconductorsubstrate; etching a portion of the semiconductor substrate between theisolation regions to form a trench; and performing a plurality of loops,each including growing a semiconductor seed layer comprising a firstportion in the trench, and a second portion outside of the trench;filling a protection layer into the trench; etching back the protectionlayer, so that the protection layer has a top surface lower than topsurfaces of the isolation regions; etching portions of the semiconductorseed layer; removing the protection layer; and growing an epitaxy regionfrom the semiconductor seed layer. In an embodiment, the semiconductorseed layer is formed using atomic layer deposition. In an embodiment,the semiconductor seed layer is formed using chemical vapor deposition.In an embodiment, the method further includes growing an additionalsemiconductor region to fully fill the trench; performing aplanarization on the additional semiconductor region; and recessing theisolation regions so that a top portion of the additional semiconductorregion forms a semiconductor fin. In an embodiment, the growing thesemiconductor seed layer comprises growing a silicon layer. In anembodiment, the growing the semiconductor seed layer comprises growing asilicon germanium layer.

In accordance with some embodiments of the present disclosure, a deviceincludes a semiconductor substrate; isolation regions extending into thesemiconductor substrate; a first semiconductor seed layer betweenisolation regions, the first semiconductor seed layer including a firstportion on a top surface of a portion of the semiconductor substrate;and a second portion and a third portion on sidewalls of the isolationregions, wherein top surface of the second portion and the third portionare lower than top surfaces of the isolation regions; and a firstsemiconductor region between the second portion and the third portion ofthe first semiconductor seed layer, wherein the first semiconductor seedlayer and the first semiconductor region have different compositions. Inan embodiment, the device further includes a second semiconductor regionbetween the isolation regions, with the second semiconductor regionbeing over the first semiconductor region, and the first semiconductorregion and the second semiconductor region have different compositions.In an embodiment, a portion of the second semiconductor region is higherthan top surfaces of the isolation regions to form a semiconductor fin,and the device further comprises a gate stack on the semiconductor fin.In an embodiment, the first semiconductor seed layer comprises silicon,and is free from germanium therein. In an embodiment, the firstsemiconductor seed layer comprises silicon germanium.

In accordance with some embodiments of the present disclosure, a methodincludes forming isolation regions extending into a semiconductorsubstrate; etching a portion of the semiconductor substrate between theisolation regions to form a trench; forming a semiconductor seed layercomprising a first portion extending into the trench, and a secondportion outside of the trench; filling the trench with a protectionlayer, with the protection layer being on a bottom portion of thesemiconductor seed layer; etching back the semiconductor seed layer andthe protection layer, with top surfaces of remaining portions of thesemiconductor seed layer and the protection layer being lower than topsurfaces of the isolation region; and removing the protection layer. Inan embodiment, the semiconductor seed layer is etched after theprotection layer is etched, and the semiconductor seed layer is etchedusing a remaining portion of the protection layer as an etching mask. Inan embodiment, the semiconductor seed layer and the protection layer areetched in a common process. In an embodiment, the method furtherincludes selectively growing a semiconductor region in a space left bythe removed protection layer. In an embodiment, the semiconductor seedlayer and the semiconductor region are formed of different semiconductormaterials.

In accordance with some embodiments of the present disclosure, a deviceincludes a semiconductor substrate; isolation regions extending into thesemiconductor substrate; and a plurality of semiconductor regionsbetween the isolation regions, with an upper one of the plurality ofsemiconductor regions being overlapping a respective lower one of theplurality of semiconductor regions, wherein each of the plurality ofsemiconductor regions comprises: a seed layer; and an epitaxysemiconductor region over a bottom portion of the seed layer, whereinthe seed layer and the epitaxy semiconductor region are formed ofdifferent semiconductor materials. In an embodiment, the seed layercomprises: a bottom portion; and sidewall portions over, and connectedto opposite end portions of, the bottom portion of the seed layer,wherein the epitaxy semiconductor region is between the sidewallportions of the seed layer. In an embodiment, the seed layer is formedof silicon, and the epitaxy semiconductor region is formed of silicongermanium.

In accordance with some embodiments of the present disclosure, a deviceincludes a semiconductor substrate; isolation regions extending into thesemiconductor substrate; and a semiconductor region between oppositeportions of the isolation regions, the semiconductor region including aseed layer including a bottom portion; and sidewall portions contactingsidewalls of the isolation regions, wherein the bottom portion and thesidewall portions form a basin; and an epitaxy semiconductor region inthe basin, wherein the epitaxy semiconductor region and the seed layerare formed of different semiconductor materials. In an embodiment, thedevice further includes an additional semiconductor region over thesemiconductor region, wherein the additional semiconductor regionincludes a lower portion between the opposite portions of the isolationregions; and an upper portion protruding higher than top surfaces of theisolation regions.

The foregoing outlines features of several embodiments so that thoseskilled in the art may better understand the aspects of the presentdisclosure. Those skilled in the art should appreciate that they mayreadily use the present disclosure as a basis for designing or modifyingother processes and structures for carrying out the same purposes and/orachieving the same advantages of the embodiments introduced herein.Those skilled in the art should also realize that such equivalentconstructions do not depart from the spirit and scope of the presentdisclosure, and that they may make various changes, substitutions, andalterations herein without departing from the spirit and scope of thepresent disclosure.

What is claimed is:
 1. A method comprising: etching a portion of asemiconductor material between isolation regions to form a trench;forming a first semiconductor seed layer extending on a bottom surfaceand sidewalls of the trench; etching-back the first semiconductor seedlayer until a top surface of the first semiconductor seed layer is lowerthan top surfaces of the isolation regions; performing a first selectiveepitaxy to grow a first semiconductor region from the firstsemiconductor seed layer; and forming an additional semiconductor regionover the first semiconductor region to fill the trench.
 2. The method ofclaim 1, wherein the etching-back the first semiconductor seed layercomprises: forming a protection layer over the first semiconductor seedlayer; etching-back the protection layer, wherein the etching-back thefirst semiconductor seed layer is performed using the protection layeras an etching mask; and before the first semiconductor seed layer isgrown, removing the protection layer.
 3. The method of claim 2, whereinthe forming the protection layer comprises dispensing a photo resist. 4.The method of claim 1, wherein the first semiconductor seed layercomprises horizontal portions and vertical portions having thicknessesclose to each other.
 5. The method of claim 1, wherein after the firstsemiconductor seed layer is etched back, the first semiconductor seedlayer has a basin shape.
 6. The method of claim 1, wherein the formingthe first semiconductor seed layer is nonselective, and the firstsemiconductor seed layer is grown from both surfaces of the isolationregions and a top surface of the semiconductor material.
 7. The methodof claim 1, wherein the forming the first semiconductor seed layercomprises growing a silicon layer, with the silicon layer free fromgermanium.
 8. The method of claim 1, wherein the forming the firstsemiconductor seed layer comprises growing a silicon germanium layer. 9.The method of claim 1 further comprising: forming a second semiconductorseed layer over the first semiconductor region, wherein the secondsemiconductor seed layer comprises a first portion on top surfaces ofthe isolation regions, and a second portion extending into the trench;etching-back the second semiconductor seed layer; and performing asecond selective epitaxy to grow a second semiconductor region from thesecond semiconductor seed layer, wherein the additional semiconductorregion is formed over the second semiconductor region.
 10. A methodcomprising: forming isolation regions adjacent to a surface of asemiconductor substrate; etching a portion of the semiconductorsubstrate between the isolation regions to form a trench; and performinga plurality of loops, each comprising: growing a semiconductor seedlayer comprising a first portion in the trench, and a second portionoutside of the trench; filling a protection layer into the trench;etching back the protection layer, so that the protection layer has atop surface lower than top surfaces of the isolation regions; etchingportions of the semiconductor seed layer; removing the protection layer;and growing an epitaxy region from the semiconductor seed layer.
 11. Themethod of claim 10, wherein the semiconductor seed layer is formed usingatomic layer deposition.
 12. The method of claim 10, wherein thesemiconductor seed layer is formed using chemical vapor deposition. 13.The method of claim 10 further comprising: recessing the isolationregions to form a semiconductor fin, and the semiconductor fin comprisesat least a part of one of the semiconductor seed layer and one of theepitaxy regions.
 14. The method of claim 10, wherein the growing thesemiconductor seed layer comprises growing a silicon layer.
 15. Themethod of claim 10, wherein the growing the semiconductor seed layercomprises growing a silicon germanium layer.
 16. A method comprising:forming isolation regions extending into a semiconductor substrate;etching a portion of the semiconductor substrate between the isolationregions to form a trench; forming a semiconductor seed layer comprisinga first portion extending into the trench, and a second portion outsideof the trench; filling the trench with a protection layer, with theprotection layer being on a bottom portion of the semiconductor seedlayer; etching back the semiconductor seed layer and the protectionlayer, with top surfaces of remaining portions of the semiconductor seedlayer and the protection layer being lower than top surfaces of theisolation region; and removing the protection layer.
 17. The method ofclaim 16, wherein the semiconductor seed layer is etched after theprotection layer is etched, and the semiconductor seed layer is etchedusing a remaining portion of the protection layer as an etching mask.18. The method of claim 16, wherein the semiconductor seed layer and theprotection layer are etched in a common process.
 19. The method of claim16 further comprising selectively growing a semiconductor region in aspace left by the removed protection layer.
 20. The method of claim 19,wherein the semiconductor seed layer and the semiconductor region areformed of different semiconductor materials.